Never heard of an engine with two thermostats - learn something new every day. A quick search found the info below from a Dodge Caliber forum
Here:You might have to pull the thermostats out and physically check to see if one (or both) are stuck open, although I think you'd get a check engine light / DTC code for engine temp low.
According to the dealer service manual:
The engine cooling thermostat is a wax pellet driven, reverse poppet choke type. The thermostat is designed to provide the fastest warm up possible by preventing leakage through it and to guarantee a minimum engine operating temperature of 88 to 93°C (192 to 199°F).
The primary thermostat starts to open at 77° C (171° F) and is fully open at 89° C (193° F).
The secondary thermostat starts to open at 95° C (203°F) and is fully open at 108° C (226° F).
The thermostat is operated by a wax filled chamber (pellet) which is sealed. When coolant reaches a predetermined temperature, the wax expands enough to overcome the closing spring and water pump pressure, which forces the thermostat to open. Coolant leakage into the wax pellet will cause a thermostat to fail in the open position. Do not attempt to free-up a stuck open thermostat.
If the thermostat is stuck open or allows coolant leakage through it, the engine will not operate at the proper temperature for obtaining engine fuel efficiency, performance and emissions levels. If this condition occurs, a diagnostic trouble code will be set and a MIL light will be turned on. Refer to the Powertrain Diagnostic Procedures manual for further information and diagnostics provided.
Thermostat diagnostics is included in powertrain control module’s (PCM) programing for on-board diagnosis. The malfunction indicator light (MIL) will illuminate and a diagnostic trouble code (DTC) will be set when an “open too soon” condition occurs. Do not change a thermostat for lack of heater performance or temperature gauge position, unless a DTC is present. For other probable causes, (Refer to 7 - COOLING/ENGINE - DIAGNOSIS AND TESTING). Thermostat failing shut is the normal long term mode of failure, and normally, only on high mileage vehicles. The temperature gauge will indicate this (Refer to 7 - COOLING/ENGINE - DIAGNOSIS AND TESTING).