Polycarbonate makes great bullet resistant windows. I saw a display at TAP plastics once. They had something like a 2" thick sheet of Acrylic (plexiglas) that they shot with all sorts of small calibers - 9mm, .45, .44 mag, .22 mag. It was seriously cracked up where the rounds hid and It put cracks all the way through but it just barely managed to stop things like the .44.
Then next to it was a sheet of Polycarbonate - similar types of rounds, but the sheet was only half an inch thick. It didn't have a single crack in it - just smooth deformations where the bullets hit. Very impressive.
I also made the mistake one day, when CD-R's were expensive and unreliable, of trying to shoot one with a pellet gun in frustration. I took it outside and shot it - only to recieve a riccochet to the eye - ow. It never broke the CD, they're made of Polycarbonate. Thankfully my eye is fine. I also noticed that my polycarbonate sunglasses are very scratch resistant, making me hesitant to believe that acrylic really is better at scratch resistance, but it's possible that it's also coated in some manner. Long story short, if you want to make bulletproof Fiero windows... go with Polycarbonate. Otherwise I guess Acrylic is easier to work.