Replacing the bolts with studs is an excellent idea. If you cant find volkswagon try Rodney Dickmans set. The link is in the vendors page. I have them, good quality, fast service too.
Some one correct me if I am in error, from what I have read on the forum, the blown out exhaust gaskets cause burned valves.
Do a search on bolt extraction and also on manifold gaskets. Arm your self with plenty of 13mm sockets, wrenches, and ratchet wrenches.
Also be prepared for the worst. Some manifold jobs go well and other folks have difficulties.
We will be here for you, keep us posted, Ok?
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jetman
Silver 86 SE 2M6 4-speed, with "check wallet light"