This Is Not as simple as Material used.
Aluminum heater cores can be same, better or worse Performance then OE Brass
because Performance depends on many things.Example: Fin density alone effect heat transfer to air. Too little or Too much fin space and air doesn't heat at low or high or any blower speeds.
Regardless of Material, If new one is not an exact fit replacement then you likely need to adjust the fit or air "leaks" can bypass the core reducing heating same as heat/cool door problems or just that door set to cool.
That's ignoring many are missing foam "gasket(s)" around the pipes to the core/ac going thru the heater box front and other problems. That can kill heating and/or cooling by letting air to move in the wrong places.
Brass/Copper cores are made of stamp flat metal then soldered every where. Most times the solder failed at a thin spot and leaks.
You may think is better but wait a few years to often have same failures. More so if you have weak coolant mix. Worse if new brass cores have Lead Free solders to meet RoHS etc.
RoHS and related rules/laws not limited to electronics for most things made now. USEPA and others have new rules affecting how most things are made like This is why most "Semi-metallic" and other Brake pads/shoes are or have moved to low copper formulas.
I haven't seen let alone test Fiero AL cores to tell if they have problems or not. You can't trust catalog/online pictures.
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Dr. Ian Malcolm: Yeah, but your scientists were so preoccupied with whether or not they could, they didn't stop to think if they should.
(Jurassic Park)
The Ogre's Fiero Cave