There are loads of performance parts available for the Duke. Clifford Performance offers pistons, cams and I believe even headers are still availble. Trouble is that with this engine you can only do so much. There is one guy on this forum who claims to have squeezed the Duke to about 200 HP but I believe that he was plagued with some blow ups.
I guess it all comes down to how much HP you want. IMO, much above about 135 HP these engines start to operate in the "gray zone". I believe that the Duke is a fine engine for the purpose for which it was designed- a low revving economy engine. If you want the 135 HP at an affordable cost, you might try experimenting with a 30-50 HP shot of nitrous, but make sure that you don't run lean!!!!!
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87GT 3.4 Turbo Best 0-60 5.2 seconds
http://www.turbochargerpower.com/turbo.htm